Try disabling the PC MASTER OUTPUT first; it's that checkbox below the audio device selection [DDJ-RB ASIO].
Every time I try to change one of my 3 options of outputs (being 1. Master Output 2. Headphones Output 3. Booth Output) It will change the rest to the same one. The beginning of each one has DDj-RB ASIO : MASTER + [Name of Device] if that helps. 
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Try disabling the PC MASTER OUTPUT first; it's that checkbox below the audio device selection [DDJ-RB ASIO].
This is what it shows when I do that.
Okay, so are you unable then to select the DDJ-RB ASIO : MASTER for the master output, and the DDJ-RB ASIO : PHONES for the headphone output?
It works, I just want to be able to play audio out of the microphone I use and be able to hear it.
The names are DDJ-RB ASIO : MASTER + Line in (Voicemod) and DDJ-RB ASIO : MASTER + Headphones (High def Audio)
Sorry, I don't understand what you mean in that last post.